期刊
SYNLETT
卷 26, 期 4, 页码 441-448出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1380156
关键词
palladium; cross-coupling; cyclopropanols; strain; C-C cleavage; homoenolates
资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Boehringer Ingelheim (Canada) Ltd.
- York University
- OGS
- QEIIST
Strained alcohols have featured prominently in a wide array of transition-metal-catalyzed cross-coupling reactions, but methods involving cyclopropanols have only been developed relatively recently. In this account, we describe our group's work in this area, and we provide a concise summary of other palladium-catalyzed methods for C-C bond-forming reactions using cyclopropanols. 1 Introduction 2 Cross-Coupling Reactions Using Strained Tertiary Alcohols 3 Base-or Acid-Mediated Ring-Opening Reactions of Strained Alcohols 4 Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols 4.1 Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols with Aryl Halides 4.2 Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols with Benzyl Halides 4.3 Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols with Acyl Halides 4.4 Direct Arylation Using Cyclopropanol-Derived Palladium Homoenolates 4.5 Synthesis of Quinolines from Cyclopropanols 5 Conclusions
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