期刊
SYNLETT
卷 26, 期 4, 页码 531-536出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379606
关键词
C-H arylation; benzothiophene; benzofuran; MIDA boronate; bis(alkoxo)palladium(II) complex
资金
- National Science Foundation of China [21172200]
With high regioselectivity, a series of benzoheterocyclic compounds were synthesized via palladiium-catalyzed phosphine-free C-H arylation of benzothiophenes/benzofurans with aryl MIDA boronates at 30-50 degrees C in moderate to excellent yields. MIDA boronates were used in C-H arylation of heterocycles for the first time. Under the optimal conditions, the benzothiophenes could be transformed into the beta-arylbenzothiophenes, and the benzofurans gave only alpha-aryl-substituted products.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据