期刊
SYNLETT
卷 26, 期 20, 页码 2866-2869出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1560660
关键词
nonmetal-catalyzed; oxazoles; sp(3) C-H functionalization; high yield; amino acids
资金
- Fundamental Research Funds for the Central Universities, P. R. of China
A nonmetal-catalyzed process for the synthesis of polysubstituted oxazoles from inexpensive and readily available -amino acids and methyl ketones is established. This reaction is proposed to achieve oxidative cleavage of C(sp(3))-H bonds, followed by decarboxylation and annulation. The mild reaction conditions employed in both cases enable the tolerance of a wide range of functional groups as well as high reaction efficiency.
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