期刊
SYNLETT
卷 26, 期 14, 页码 1915-1922出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378712
关键词
atropisomers; organocatalysis; enantioselective synthesis; desymmetrization; dynamic kinetic resolution
资金
- University of Bologna
Atropisomers are compounds in which chirality arises from hindered rotation along the carbon-carbon or carbon-heteroatom single bond. Recently, organocatalysis appeared to be a rapid, valuable, and efficient strategy for their preparation in an enantioselective manner. In this report a general overview of the most important organocatalyzed atroposelective transformations will be given pointing out in particular the specific role played by the catalyst. 1 Dynamic Kinetic Resolution 2 Desymmetrization of Biaryls 3 Direct Synthesis of Biaryls 4 Asymmetric Friedel-Crafts Amination of Naphthols 5 N-Alkylation via Phase-Transfer Catalysis 6 Desymmetrization of N-Arylmaleimides
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