4.6 Article

An extended infrared study of the p, T phase diagram of the p-doped Cu-O plane

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NEW JOURNAL OF PHYSICS
卷 13, 期 -, 页码 -

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IOP PUBLISHING LTD
DOI: 10.1088/1367-2630/13/12/123009

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  1. European Community [226716]

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The ab-plane optical conductivity of 11 single crystals, belonging to the families Sr2-xCuO2Cl2, Y1-xCaxBa2Cu3O6, Bi2Sr2-xLaxCuO6 and Bi2Sr2CaCu2O8, has been measured with hole concentrations p between 0 and 0.18 and for 6 K <= T <= 500 K to obtain an infrared picture of the p, T phase diagram of the Cu-O plane. At extreme dilution (p = 0.005), a narrow peak is observed at 1570 cm(-1) (195 meV), which we assign to a single-hole bound state. For increasing doping, that peak broadens into a far-infrared (FIR) band whose low-energy edge sets the insulating gap. The insulator-to-metal transition (IMT) occurs when the softening of the FIR band closes the gap, thus evolving into a Drude term. In the metallic phase, a multi-band analysis identifies a mid-infrared band which weakly depends on temperature and softens for increasing p, while the extended-Drude analysis leads to an optical scattering rate larger than the frequency, as was found in other cuprates. The infrared spectral weight W(T) is consistent with a Fermi liquid renormalized by strong correlations, provided that the T-4 term of the Sommerfeld expansion is included above 300 K. In the superconducting phase, the optical response of single-layer Bi2Sr2-xLaxCuO6 at optimum doping is similar to that of the corresponding optimally doped bilayer Bi2Sr2CaCu2O8.

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