期刊
NEW JOURNAL OF CHEMISTRY
卷 38, 期 8, 页码 3673-3677出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj00731j
关键词
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资金
- National Natural Science Foundation of China (NSFC) [21035005]
- Cultivation Plan of Chongqing Science and Technology Commission for 100 Outstanding Science and Technology Leading Talents
A one step synthesis of water-soluble luminescent copper nanoclusters (CuNCs) reduced and protected by histidine is reported. When excited at 350 nm, the as-synthesized CuNCs exhibit luminescence centered at 456 nm with a quantum yield of 1.6%, which is different from that of histidine alone under the same experimental conditions. Upon addition of guanosine 5'-triphosphate (GTP), the emission of CuNCs is gradually quenched. While other nucleoside triphosphates including ATP, CTP and UTP as well as some inorganic anions such as P2O74-, PO43-, and CH3COO- have no such quenching effect, which indicates that the nucleobase instead of the phosphate anion plays an important role in the emission quenching of CuNCs. The most efficient quenching of the CuNCs induced by GTP can be ascribed to the most reducing ability of guanine among the other nucleobases. This interesting experimental result demonstrates that the as-synthesized CuNCs can be applied to sensing of GTP.
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