期刊
NEW JOURNAL OF CHEMISTRY
卷 38, 期 7, 页码 3236-3241出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj00280f
关键词
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资金
- National Natural Science Foundation of China [51362018, 21163010]
- Key Project of Chinese Ministry of Education [212183]
- Natural Science Funds for Distinguished Young Scholars of Gansu Province [1111RJDA012]
Three-dimensional (3D) Co3O4-Ni-3(VO4)(2) heterostructured nanorods on nickel foam with excellent electrochemical behavior were synthesized by a facile strategy. A growth mechanism was proposed to explain the formation of the composite. The composite combined separately the advantages of the good rate capability of Co3O4 and the high specific capacitances of Ni-3(VO4)(2), and showed higher specific capacitances than Co3O4 and better rate capability than Ni-3(VO4)(2). A maximum specific capacitance of 1401 F g(-1) and energy density of 31.2 Wh kg(-1) were achieved at a current density of 0.5 A g(-1), and 70.3% of this value was retained at a high current density of 8 A g-1. After 1000 cycles, 98.3% and 90.9% was retained at 0.5 A g(-1) and 8 A g(-1), respectively. The excellent electrochemical performance renders the composite a promising electrode for supercapacitors.
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