期刊
NEW JOURNAL OF CHEMISTRY
卷 36, 期 9, 页码 1769-1773出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj40255f
关键词
-
资金
- MEXT (Ministry of Education, Culture, Sports, Science and Technology) [24105513, 2304]
- Asahi Glass Foundation
- Hori Sciences & Arts Foundation
A series of unsymmetrical S-(bromodifluoromethyl)diarylsulfonium salts 1 were readily synthesized by treatment of corresponding (bromodifluoromethyl)arylsulfoxides 2 and substituted benzenes 3 with triflic anhydride in moderate to good yields. The unsymmetrical sulfonium salts 1 with different aryl groups having electron-donating or electron-withdrawing substituents can be nicely constructed depending on the choice of 2 and 3. Bromodifluoromethylation of alkynes was evaluated by using the selected diarylsulfonium salts 1 to provide the desired bromodifluoromethylated alkynes in moderate to good yields.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据