期刊
NEW JOURNAL OF CHEMISTRY
卷 36, 期 2, 页码 380-385出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1nj20375d
关键词
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资金
- National Natural Science Foundation of China [20973178]
- National Basic Research Program of China (973 Program) [2011CB808600]
- Chinese Academy of Sciences
A new kind of codendrimer consisting of a Frechet-type dendron and a Tomalia-type PAMAM dendron has been synthesized via a liquid-phase approach, which could easily be purified using a simple precipitation method without the need for chromatographic separation. Functionalization at the periphery of a PAMAM dendron with bis(diphenylphosphinomethyl) amino groups led to a novel class of Janus dendritic phosphines. Their use as a recyclable homogeneous catalyst has been demonstrated with the Pd-catalyzed Suzuki coupling reaction.
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