期刊
NEW JOURNAL OF CHEMISTRY
卷 36, 期 11, 页码 2209-2214出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj40469a
关键词
-
资金
- CSIR, New Delhi
Aldimine formed in situ on bimolecular reductive coupling in the presence of zinc and accelerated by indium(III) chloride in water afforded N,N'-diphenyl-1,2-diaryl-1,2-diamino ethane which on aza-Michael addition with alpha,beta-unsaturated ketone and subsequent dehydrative cycloaddition yielded monocyclic 1,4-diazepine in excellent yield and with high diastereoselectivity in one-pot. The whole reaction sequence proceeded smoothly with quantitative conversion of reactants into product. The reaction pathway was supported by isolation of N,N'-diphenyl-1,2-diaryl-1,2-diamino ethane and its conversion into product by reaction with alpha,beta-unsaturated ketone under similar reaction conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据