期刊
NEW JOURNAL OF CHEMISTRY
卷 36, 期 3, 页码 668-673出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj20898a
关键词
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资金
- Entente Cordiale Scholarship
A ditopic ligand (1), containing two tridentate bis(acylhydrazone) subunits and bearing both long alkyl chains and hydrogen-bonding groups, has been synthesised. Metal cation binding in the presence of a base leads to hierarchical self-assembly, forming first a neutral [2 x 2] grid-type complex (2) that hierarchically assembles into metallosupramolecular polymer gels in toluene.
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