期刊
NEW JOURNAL OF CHEMISTRY
卷 33, 期 3, 页码 612-619出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b816790g
关键词
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资金
- Czech Science Foundation [203/06/0738, 203/07/1424]
- Ministry of Education, Youth and Sports of the Czech Republic [OC134]
- Grant Agency of the Academy of Sciences of the Czech Republic [IAA400720706]
A series of diureido-calix[4]arenes immobilised in the 1,3-alternate conformation was synthesised and systematically studied for their complexation ability. As revealed by H-1 NMR and UV/vis titrations, this structural motif leads to very efficient ligands for anion recognition with high binding constants in nonpolar solvents. The comparison with the corresponding ligands possessing the cone conformation indicates that diureido-calix[4]arene in a 1,3-alternate conformation are very promising anion receptors with pronounced binding ability towards carboxylates.
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