期刊
NEW JOURNAL OF CHEMISTRY
卷 33, 期 5, 页码 1070-1075出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b822104a
关键词
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资金
- NSF of China [20525310, 20773167, 20731005]
- 973 Program of China [2007CB815302]
- Leverhulme Trust
Modification of Fe-tricarboxylate based metal-organic gels yielded tert-butyl substituted or phosphine-functionalised gels in alcohols or DMF, which were prepared from 5-tert-butylisophthalic acid and 5-diphenylphosphanylisophthalic acid, respectively. Owing to their permeability, such phosphine-functionalised metal-organic gels can act as a new type of functionalisable porous scaffold. The phosphorus-containing gel was subsequently functionalised with Pd(II) by immersion in a solution of Pd(COD)Cl-2 (COD = 1,5-cyclooctadiene). The subsequently functionalised Pd(II)-immobilised gel and its xerogel/aerogel showed high activity in the catalysis of Suzuki C-C coupling comparable to unsupported complexes. The gel/xerogels could be reused under ambient atmosphere.
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