4.7 Article

EXAFS and DFT study of the cadmium and lead adsorption on modified silica nanoparticles

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2015.06.093

关键词

Cadmium; Lead; Silica nanoparticles; EXAFS; DFT; MEH-PPV

资金

  1. Grant PICT from Agencia Nacional de Promocion Cientifica y Tecnologica, (ANPCyT, Argentina) [0686]
  2. PIP (CONICET, Argentina) [01035]
  3. LNLS (Brasil) [XAFS1-14534]

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Silica nanoparticles of 7 nm diameter were modified with (3-aminopropyl) triethoxysilane (APTES) and characterized by CP-MAS C-13 and Si-29 NMR, FTIR, zeta potential measurements, and thermogravimetry. The particles were shown to sorb successfully divalent lead and cadmium ions from aqueous solution. Lead complexation with these silica nanoparticles was clearly confirmed by EXAFS (Extended X-ray Absorption Fine Structure) with synchrotron light measurements. Predicted Pb-N and Pb-C distances obtained from quantum-chemical calculations are in very good agreement with the EXAFS determinations. The calculations also support the higher APTES affinity for Pb2+ compared to Cd2+. (C) 2015 Elsevier B.V. All rights reserved.

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