Selective recognition of Ni2+ ion based on fluorescence enhancement chemosensor

A new enhancing fluorescent chemosensor was introduced for selective and sensitive determination of nickel ions based on 2-(1-H-benzo[d]imidazol-2yl)-N-phenyl hydrazine carbothioamide (L). L has an intrinsic fluorescent emission which enhances in presence of nickel ions in CH3CN/H2O (70:30, v/v) solution. The fluorescence enhancement of L is attributed to a 1:1 complex formation between L and Ni2+ ion which has been used for selective detection of Ni2+ ion. At the optimum conditions, the fluorescence intensity of L at 352 nm enhances linearly by the concentration of nickel ion from 1.6 x 10(-5) to 1.6 x 10(-7) M and detection limit of 7.9 x 10(-8) M. The new fluorescent probe exhibited high selectivity to Ni2+ ion over the other common mono, di-and trivalent cations. (C) 2014 Elsevier B.V. All rights reserved.