期刊
SOLID STATE IONICS
卷 283, 期 -, 页码 75-80出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ssi.2015.10.014
关键词
Solid electrolyte; Ionic conductivity; Lithium-sulfur battery; Composite electrolyte; Lithium thiophosphate
资金
- U.S. Department of Energy, Office of Science, Materials Sciences and Engineering Division
- Division of Scientific User Facilities Division, U.S. DOE
- Higher Education Research Experiences (HERE) at Oak Ridge National Laboratory
- National Science Foundation [DGE-1148903]
- U.S. Government [DE-AC05-00OR22725]
Solid electrolytes are the subject of intense study partly because of their use in safer, high energy density, all-solid-state lithium-ion batteries. The addition of solid oxide fillers has been previously explored as a way to increase the ionic conductivity in composite electrolytes; however, no comparative study of the effect of both ion-conducting and non-conducting oxides on solid lithium superionic conductor electrolyte is reported. Nano-crystalline beta-Li3PS4 (LPS) was recently shown to have anomalous high ionic conductivity, but it was found that this property can be further enhanced. This study examines the effect of three solid oxide fillers (Li6ZnNb4O14, Al2O3, and SiO2) in composites with LPS for the enhancement of the parent electrolyte. The electrolytes' processability, ionic conductivity, activation energy, and stability against metallic lithium are presented to gain a complete understanding on the effect of solid oxide fillers on LPS while elucidating the significant enhancement of LPS through the addition of Li6ZnNb4O14 or Al2O3. (C) 2015 Elsevier B.V. All rights reserved.
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