期刊
SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 137, 期 -, 页码 311-318出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.solmat.2015.02.024
关键词
Nonionic surfactant; PEDOT:PSS; Wetting property; Electrical conductivity; Vacuum-free organic solar cells
资金
- Recruitment Program of Global Youth Experts
- Fundamental Research Funds for the Central Universities, HUST [2014YQ013]
- Natural Science Foundation of Hubei Province [2012FFC05401]
- Postdoctoral Science Foundation of China [2014M562016]
- Foundation of Hubei Educational Committee [Q20122512]
In this work, we report a nonionic surfactant (polyethylene glycol 2,5,8,11-tetramethyl-6-dodecyne-5,8-diol ether, PEG-TmDD) that can improve the wetting property of PEDOT:PSS aqueous solution on the organic photoactive layer and simultaneously enhance the electrical conductivity of PEDOT:PSS film up to 526 S/cm. Furthermore, the conductivity enhancement is significantly dependent on the thermal annealing, which is contrary to the conductivity behavior of PEDOT:PSS film prepared from the formulation added with ethylene glycol (EG) where the conductivity is almost independent of the thermal annealing. The temperature dependence of the conductivity of PEDOT:PSS by PEG-TmDD is possibly ascribed to decomposition of PEG-TmDD into EG and TmDD during thermal annealing. With the high conductivity and good wetting on the active layer, PEDOT:PSS mixed with PEG-TmDD is used as the top electrode for organic solar cells. The cells exhibit a fill factor of 60% and a power conversion efficiency of 4.1% using poly(3-hexylthiophene):indene-C60 bis-adduct as the active layer. The results indicate that the new formulation of PEDOT:PSS mixed with PEG-TmDD is suitable for preparing a top electrode for vacuum-free organic solar cells. (C) 2015 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据