Influence of Hadean crust evident in basalts and cherts from the Pilbara Craton

Application of the Sm-147-Nd-143 and Sm-146-Nd-142 chronometers has suggested that the initial differentiation of Earth's mantle into enriched and depleted reservoirs may have begun within the first 100-200 million years of Earth's history(1). However, little is known about the differentiation of the early crust; although evidence has suggested the presence of enriched crustal material(2-5), data regarding the nature and composition of this crust are limited. Here we present Sm-147-Nd-143 data from the weakly metamorphosed basalt and layered chert-barite successions from the Dresser Formation of the Pilbara Craton, Western Australia. The Sm-Nd isochron indicates an age of 3.49 +/- 0.10 billion years, in agreement with previous estimates from Pb-Pb (ref. 6) and U-Pb ( ref. 7) dating, which indicates that the Sm-Nd system has not been reset. Our measured epsilon(Nd) value of -3.3 +/- 1.0 for the rocks at this site is consistent with formation from an older protolith. On the basis of our modelling of trace element and isotopic compositions from these rocks, we suggest that the older component was crustal in nature, and differentiated from the convective mantle more than 4.3 billion years ago.