期刊
NATURE CHEMISTRY
卷 5, 期 12, 页码 1035-1041出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/NCHEM.1780
关键词
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资金
- DARPA [N66001-09-1-2088]
- CITRIS [73-2010]
- UC Merced start-up
- National Science and Technology Key Project of China [2012AA020204]
Mechanoresponsive polymers hold great technological potential in drug delivery, 'smart' optical systems and microelectromechanical systems. However, hysteresis and fatigue (associated with large-scale polymer chain rearrangement) are often problematic. Here, we describe a polyarylamide film that contains s-dibenzocyclooctadiene (DBCOD), which can generate unconventional and completely reversible thermal contraction under low-energy stimulation. The films exhibit a giant negative thermal expansion coefficient of approximately -1,200 ppm K-1 at ambient or near-ambient temperatures, much higher than any known negative-thermal-expansion materials under similar operating conditions. Mechanical characterization, calorimetry, spectroscopic analysis and density-functional theory calculations all point to the conformational change of the DBCOD moiety, from the thermodynamic global energy minimum (twist-boat) to a local minimum (chair), as the origin of this abnormal thermal shrinkage. This newly identified, low-energy-driven, thermally agile molecular subunit opens a new pathway to creating near-infrared-based macromolecular switches and motors, and for ambient thermal energy storage and conversion.
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