期刊
NANOTECHNOLOGY
卷 23, 期 37, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/23/37/375705
关键词
-
资金
- Australian Research Council [LP0209078]
- Knowledge Innovation Program of the Chinese Academy of Sciences [KZCX2-YW-QN101/GIGCAS1534]
- National Natural Science Foundation of China [41072032]
- Australian Research Council [LP0209078] Funding Source: Australian Research Council
The surfaces of naturally occurring halloysite nanotubes were functionalized with gamma-aminopropyltriethoxysilane (APTES), which was found to have a substantial effect on the loading and subsequent release of a model dye molecule. APTES was mostly anchored at the internal lumen surface of halloysite through covalent grafting, forming a functionalized surface covered by aminopropyl groups. The dye loading of the functionalized halloysite was 32% greater than that of the unmodified sample, and the release from the functionalized halloysite was dramatically prolonged as compared to that from the unmodified one. Dye release was prolonged at low pH and the release at pH 3.5 was approximately three times slower than that at pH 10.0. These results demonstrate that organosilane functionalization makes pH an external trigger for controlling the loading of guest on halloysite and the subsequent controlled release.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据