期刊
NANOTECHNOLOGY
卷 22, 期 32, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/22/32/325706
关键词
-
资金
- Ministry of Science, Technology and Innovation, Malaysia
Cyclic tensile and compressive deformation is applied to cellulose nanowhisker-epoxy resin based model nanocomposites. The molecular deformation of the cellulose nanowhiskers within the epoxy resin matrix is followed using a Raman spectroscopy technique, whereby shifts in the position of a band located at similar to 1095 cm(-1) are shown to correlate directly with a breakdown in the interfaces between the resin and the nanowhiskers and between nanowhiskers themselves. A theoretical model is used to determine the dissipation of energy at the interfaces between whiskers and at the whisker-matrix interface. This approach is shown to be useful for interpreting the local micromechanics of these materials by providing a quantitative measure of the quality of the interface.
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