期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 156, 期 -, 页码 472-479出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2015.10.037
关键词
ZIF-8; Light naphtha; n-pentane; Isopentane; Adsorption separation
资金
- National Science Foundation of China [51476074]
- Research and Innovation Project for College Graduates of Jiangsu Province [KYLX0765]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Adsorption equilibrium and kinetic data is essential for the design of an adsorption process. In this work, the adsorption isotherms of n-pentane/isopentane on zeolitic imidazolate framework material (ZIF-8) were measured at 308, 343 and 373 K over the pressure range from 0 to 9.7 kPa by a gravimetric system. The equilibrium adsorption capacity at 303 K and 9.7 kPa is 0.2504 g g(-1) for n-pentane and 0.1439 g for isopentane. Langmuir model was used to fit the adsorption isotherms. The adsorption kinetics of n-pentane/isopentane was studied at 308 K in the pressure range from 0 to 69.9 kPa. The data was well fitted with linear driving force model (LDF) model. The adsorption rate constant of n-pentane is from 0.0019 to 0.0326 s(-1), which is higher than that of isopentane, represented 0.0007-0.0036 s(-1). The adsorption selectivity of n-pentane/isopentane on ZIF-8 was contrast by the measurement of the binary breakthrough experiments at 343 K, 363 K and 393 K in the partial pressure of 7 kPa. When the adsorption temperature is 363 K, the adsorption selectivity of n-pentane/isopentane on ZIF-8 reaches the maximum 55. Compared with 5A molecular sieve, the desorption temperature of n-pentane on ZIF-8 was analyzed by temperature-programmed-desorption (TPD) method. The peak temperature of n-pentane desorption on ZIF-8 is 361 K. However are 392 K and 443 K on a 5A molecular sieve. Thus, ZIF-8 is more selective or preferential adsorption for n-pentane in comparison to isopentane molecules at low temperature. (C) 2015 Elsevier B.V. All rights reserved.
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