期刊
NANOSCALE RESEARCH LETTERS
卷 5, 期 3, 页码 518-523出版社
SPRINGEROPEN
DOI: 10.1007/s11671-009-9519-z
关键词
Polypyrrole; Film; Sodium salicylate; Tiron; Supercapacitor; Capacitance; Electropolymerization
Polypyrrole films were deposited by anodic electropolymerization on stainless steel substrates from aqueous pyrrole solutions containing sodium salicylate and tiron additives. The deposition yield was studied under galvanostatic conditions. The amount of the deposited material was varied by the variation of deposition time at a constant current density. SEM studies showed the formation of porous films with thicknesses in the range of 0-3 mu m. Cyclic voltammetry data for the films tested in 0.5 M Na2SO4 solutions showed capacitive behavior and high specific capacitance (SC) in a voltage window of 0.9 V. The films prepared from pyrrole solutions containing tiron showed better capacitive behavior compared to the films prepared from the solutions containing sodium salicylate. A highest SC of 254 F g(-1) was observed for the sample with a specific mass of 89 mu g cm(-2) at a scan rate of 2 mV s(-1). The SC decreased with an increasing film thickness and scan rate. The results indicated that the polypyrrole films deposited on the stainless steel substrates by anodic electropolymerization can be used as electrodes for electrochemical supercapacitors (ES).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据