Silver nitrate induces spontaneous room temperature transformation of ZIF-8 into a composite of ZnO nanorods embedded in a ZIF-8 matrix. This first example of reverse transformation of ZIF-8 into ZnO is a convenient method for generating fixed ZnO nanoparticles in powders as well as films and coatings. The fabricated ZnO nanorod@ZIF-8 is photocatalytically active.
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