期刊
NANOSCALE
卷 6, 期 19, 页码 11112-11120出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr03152k
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资金
- China Government
- China MOE NCET Program
- NSFC [51322204]
- Fundamental Research Funds for the Central Universities [WK2060140014]
The interactions between visible light and sub-nanometer gaps were investigated by sandwiching graphene between two layers of vertically stacked Au nanoparticles. The optical properties of such a hybrid film have been effectively tuned by embedding a monolayer graphene, enabling a suppressed transmission of similar to 16% accompanied by a red-shift of the resonant wavelength. Finite element simulations have shown that the strong coupling between two layers of plasmonic Au nanoparticles leads to an electric field enhancement of up to 88 times in graphene defined vertical gaps, in contrast to that of 14 times in the horizontal gaps between Au nanoparticles formed in the fabrication process. In addition, the size of gaps and thus the field enhancement can be readily tuned by the number of graphene layers sandwiched between Au nanoparticles. When being used as surface-enhanced Raman scattering (SERS) substrates, the Au nanoparticle/graphene/Au nanoparticle structures have demonstrated high Raman enhancement factors of up to 1.6 x 10(8) for RhB and 2.5 x 10(8) for R6G, and a detection limit of as low as 0.1 nM for Sudan III and methylene blue molecules.
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