4.8 Article

High-purity iron pyrite (FeS2) nanowires as high-capacity nanostructured cathodes for lithium-ion batteries

期刊

NANOSCALE
卷 6, 期 4, 页码 2112-2118

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nr05851d

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资金

  1. NSF [DMR-1106184]
  2. U.S. Department of Energy, SunShot NextGen PV II program under Award [DE-EE0005330]
  3. Research Corporation SciaLog Award
  4. NSF Graduate Research Fellowship
  5. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02 06CH11357]

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Iron pyrite is an earth-abundant and inexpensive material that has long been interesting for electrochemical energy storage and solar energy conversion. A large-scale conversion synthesis of phase-pure pyrite nanowires has been developed for the first time. Nano-pyrite cathodes exhibited high Li-storage capacity and excellent capacity retention in Li/pyrite batteries using a liquid electrolyte, which retained a discharge capacity of 350 mAh g(-1) and a discharge energy density of 534 Wh kg(1) after 50 cycles at 0.1 C rate.

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