期刊
NANOSCALE
卷 5, 期 13, 页码 5896-5904出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nr01470c
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资金
- National Nature Science Foundation of China [51273051, 21174033, 21204015]
- Open Project of State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology [QA201118]
- Foundation of Heilongjiang Educational Committee [12521436]
- Open Project of State Key Laboratory of Supramolecular Structure and Materials [sklssm 201326]
- Specialized Research Joint Found for the Doctoral Program of Higher Education of China [20122301120003]
Yolk-shell composites with a movable FexOy core and mesoporous SiO2 (mSiO(2)) shell, together with Pd nanoparticles uniformly anchoring on the inner surface, were prepared. The structure and composition of as-prepared catalysts were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller measurement and Fourier-transform infrared spectroscopy, respectively. They are ideal candidates as nanoreactors for heterogeneous catalysis due to their special structure. The catalytic performance of FexOy/Pd@mSiO(2) composites was studied by the reduction of 4-nitrophenol with NaBH4 as a reducing agent. Their reaction rate constant was calculated according to the pseudo-first-order reaction equation. The catalysts could be easily recycled by an external magnetic field due to their superparamagnetic property. Besides good catalytic property, another merit of FexOy/Pd@mSiO(2) composites was high stability. We have compared the stability between FexOy/Pd@mSiO(2) and Fe3O4@C/Pd composites by ultrasonic treatment and HNO3 solution etching, the stability of the former was much better than the later.
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