期刊
NANOSCALE
卷 5, 期 13, 页码 5758-5764出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nr33632h
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资金
- National Basic Research Program of China [2010CB934700, 2013CB933003]
- National Natural Science Foundation of China [21273016, 21001013]
- Program for New Century Excellent Talents in University, Beijing Natural Science Foundation [2122035]
- Key Research Program of the Chinese Academy of Sciences [KJZD-EW-M01]
- Fundamental Research Funds for the Central Universities
Multifunctional integration is an inherent characteristic for biological materials with multiscale structures. Learning from nature is an effective approach for scientists and engineers to construct multifunctional materials. In nature, mollusks (abalone), mussels, and the lotus have evolved different and optimized solutions to survive. Here, bio-inspired multifunctional graphene composite paper was fabricated in situ through the fusion of the different biological solutions from nacre (brick-and-mortar structure), mussel adhesive protein (adhesive property and reducing character), and the lotus leaf (self-cleaning effect). Owing to the special properties (self-polymerization, reduction, and adhesion), dopamine could be simultaneously used as a reducing agent for graphene oxide and as an adhesive, similar to the mortar in nacre, to crosslink the adjacent graphene. The resultant nacre-like graphene paper exhibited stable superhydrophobicity, self-cleaning, anti-corrosion, and remarkable mechanical properties underwater.
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