期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 206, 期 -, 页码 584-591出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2014.09.106
关键词
Cu-3(PO4)(2)-deposited electrode; Cu(OH)(2); Nanostructure; Amino acid; Complexation
资金
- National Science Council of Taiwan [NSC 98-2313-B-005-031-MY3, NSC 102-2622-B-005-002-CC3]
Cu-3(PO4)(2)-deposited electrodes capable of detecting nonelectroactive alpha-amino acids (AAs) are developed by the dissolution-precipitation method. The Cu-3(PO4)(2)-dominated compounds of flake-shaped nanostructures are quickly and uniformly deposited on the surface of acicula-nanostructured Cu(OH)(2)-electrodeposited electrodes in a 100mM Na2HPO4 solution (pH 5.0) within 2h. Analysis of X-ray photoelectron spectroscopy and electrochemical kinetics shows that an oxidative reaction at +0.11 V increases the ratio of H2PO4- on the electrode surface and produces the Cu-II(H2PO4)(2) complex. Moreover, the Cu-II compounds and the AAs can form complexes to accompany the chemical oxidation of AAs and the formation of the Cu-I complex, increasing the amount of oxidative current detected via the chemical-electrochemical mechanism. The amperometric response presented good linearity and sensitivity in the range of 143-600 mu M for electroactive and nonelectroactive alpha-AAs. The Cu-3(PO4)(2)-deposited electrodes are integrated into a chromatographic separation systems as an AA sensor to have promise for the detection of biological and food samples. (C) 2014 Elsevier B.V. All rights reserved.
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