4.8 Article

High performance, freestanding and superthin carbon nanotube/epoxy nanocomposite films

期刊

NANOSCALE
卷 3, 期 9, 页码 3731-3736

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1nr10438a

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资金

  1. Beijing Municipal Education Commission [BY20108000101]
  2. Chinese Academy of Sciences [KJCX2-YW-M01]
  3. National Natural Science Foundation of China [90921012]
  4. National Basic Research Program of China [2005CB623602]

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We develop a facile, effective and filter free infiltration method to fabricate high performance, freestanding and superthin epoxy nanocomposite films with directly synthesized Sing-Walled Carbon Nanotubes (SWNTs) film as reinforcement skeleton. It is found that the thicknesses of the nanocomposite films can be easily controlled in the range of 0.5-3 mu m by dripping target amount of acetone diluted epoxy through the skeleton film. The consequent measurements reveal that the mechanical and electrical properties of SWNTs/epoxy nanocomposite films could be tailored in a quite wide range. For examples, the Young's modulus of nanocomposite films can be tuned from 10 to 30 GPa, and the electrical conductivity can be ranged from 1000 S.cm(-1) to be insulated. Moreover, high load transfer efficiency in the nanocomposite films is demonstrated by the measured ultrahigh Raman bands shift rate ( 30 +/- 5 cm(-1) /% strain) under strain. The high effective modulus is derived as 774 +/- 70 GPa for SWNTs inside this nanocomposite film.

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