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Functionalization of carbon nanotubes via Cu(I)-catalyzed Huisgen [3+2] cycloaddition click chemistry

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NANOSCALE
卷 2, 期 12, 页码 2550-2556

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nr00200c

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  1. Seoul Future Contents Convergence (SFCC) Cluster [ST090826]
  2. Ministry of Knowledge Economy (MKE) of Korea [KEIT 10033449-2009-11]

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Functionalization of carbon nanotubes is essential for achieving their mechanical, electrical, and biological functions and enhancing their dispersion in a polymer matrix. Cycloaddition reactions can play a significant role as an emerging route in this direction. This minireview focuses on covalent functionalization of carbon nanotubes using a facile approach via a Cu(I)-catalyzed Huisgen [3 + 2] cycloaddition reaction. Through this reaction, an enormous variety of molecules can be coupled onto carbon nanotubes in a very controlled manner, and may be utilized for many potential applications from nanoelectronics to bio-applications.

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