Molten-salt chemical exfoliation process for preparing two-dimensional mesoporous Si nanosheets as high-rate Li-storage anode

Two-dimensional (2D) materials have attracted enormous attention due to their functional applications in energy storage. In this work, a low-temperature molten-salt chemical exfoliation methodology is developed for producing free-standing 2D mesoporous Si through deintercalation of CaSi2 in excess molten AlCl3 at 195 degrees C. The average dimension of these sheets is 1.5 mu m, and the thickness of a single sheet is approximately 10 nm. The as-prepared 2D Si has a Brunauer-Emmett-Teller surface area of 154 m(2).g(-1) and an average pore size of 5.87 nm. With this unique structure, the 2D Si exhibits superior Li-storage performance, including a reversible capacity of 2,974 mA.h.g(-1) at 0.2 C, reversible capacities of 2,162, 1,947, and 1,527 mA.h.g(-1) at 0.8, 2, and 5 C after 200 cycles, and a capacity retention of 357 mA.h.g(-1) even at 30 C (90 A.g(-1)).