期刊
NANO RESEARCH
卷 7, 期 12, 页码 1759-1768出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-014-0535-7
关键词
molybdenum disulfide; CVD growth; large area; Raman; photo-luminescence; field-effect ransistor (FET)
类别
资金
- Basic Science Research Program [2013-056117]
- Priority Research Centers Program through the National Research Foundation of Korea (NRF) [2009-0093818]
- Ministry of Education
- National Research Foundation of Korea [2012R1A1A4A01010369, 21A20131100002] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
There has been growing research interest in the use of molybdenum disulfide in the fields of optoelectronics and energy harvesting devices, by virtue of its indirect-to-direct band gap tunability. However, obtaining large area thin films of MoS2 for future device applications still remains a challenge. In the present study, the amounts of the precursors (S and MoO3) were varied systematically in order to optimize the growth of highly crystalline and large area MoS2 layers by the chemical vapor deposition method. Careful control of the amounts of precursors was found to the key factor in the synthesis of large area highly crystalline flakes. The thickness of the layers was confirmed by Raman spectroscopy and atomic force microscopy. The optical properties and chemical composition were studied by photoluminescence (PL) and X-ray photoelectron spectroscopy. The emergence of strong direct excitonic emissions at 1.82 eV (A-exciton, with a normalized PL intensity of similar to 55 x 10(3)) and 1.98 eV (B-exciton, with a normalized PL intensity of similar to 5 x 10(3)) of the sample at room temperature clearly indicates the high luminescence quantum efficiency. The mobility of the films was found to be 0.09 cm(2)/(V.s) at room temperature. This study provides a method for the controlled synthesis of high-quality two-dimensional (2D) transition metal dichalcogenide materials, useful for applications in nanodevices, optoelectronics and solar energy conversion.
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