期刊
NANO RESEARCH
卷 7, 期 7, 页码 1007-1017出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-014-0464-5
关键词
electrocatalyst; titanium dioxide nanotube; platinum nanoflower; catalytic activity; cycle life
类别
资金
- National Outstanding Young Investigator Grant of China [51225401]
- National Natural Science Foundation of China [51002004]
- Beijing Municipal Commission of Education Foundation [KZ201010005001, KM201110005003]
- China Scholarship Council
- NSF [DMR-1120901]
To improve the contact between platinum catalyst and titanium substrate, a layer of TiO2 nanotube arrays has been synthesized before depositing Pt nanoflowers by pulse electrodeposition. Dramatic improvements in electrocatalytic activity (3x) and stability (60x) for methanol oxidation were found, suggesting promising applications in direct methanol fuel cells. The 3x and 60x improvements persist for Pt/Pd catalysts used to overcome the CO poisoning problem.
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