期刊
NANO RESEARCH
卷 8, 期 3, 页码 931-940出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-014-0574-0
关键词
electric double layer; room temperature ionic liquids; nanostructured capacitor; charging dynamics
类别
资金
- Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences
- Chinese Scholarship Council
- National Natural Science foundation of China [21276138]
- Tsinghua University Foundation [2013108930]
The charging kinetics of electric double layers (EDLs) is closely related to the performance of a wide variety of nanostructured devices including supercapacitors, electro-actuators, and electrolyte-gated transistors. While room temperature ionic liquids (RTIL) are often used as the charge carrier in these new applications, the theoretical analyses are mostly based on conventional electrokinetic theories suitable for macroscopic electrochemical phenomena in aqueous solutions. In this work, we study the charging behavior of RTIL-EDLs using a coarse-grained molecular model and constant-potential molecular dynamics (MD) simulations. In stark contrast to the predictions of conventional theories, the MD results show oscillatory variations of ionic distributions and electrochemical properties in response to the separation between electrodes. The rate of EDL charging exhibits non-monotonic behavior revealing strong electrostatic correlations in RTIL under confinement.
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