期刊
NANO RESEARCH
卷 6, 期 5, 页码 348-355出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-013-0311-0
关键词
ZnCo2O4 submicron rods; ZnO nanosheets; hierarchical heterostructure; ammonia-evaporation-induced method; Li ion battery
类别
资金
- National Research Foundation of Korea (NRF)
- Korea government (MEST) [2012-0008669, 2009-0094046, 2012M1A2A2671802,, 2012R1A2A2A01045382]
- Global Frontier RAMP
- D Program on Center for Multiscale Energy System
- National Research Foundation under the Ministry of Education, Science and Technology, Korea [0420-20110156]
- National Research Foundation of Korea [2009-0094046, 2012M1A2A2671802, R31-2012-000-10075-0, 2011-0031574] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We report the direct synthesis of ZnCo2O4 and ZnO/ZnCo2O4 submicron rod arrays grown on Ni foil current collectors via an ammonia-evaporation-induced method by controlling the ratio of Zn to Co. These three-dimensional (3D) hierarchical self-supported nanostructures are composed of one-dimensional (1D) ZnCo2O4 rods and two-dimensional (2D) ZnO nanosheet bands perpendicular to the axis of the each ZnCo2O4 rod. We carefully deal with the heteroepitaxial growth mechanisms of hexagonal ZnO nanosheets from a crystallographic point of view. Furthermore, we demonstrate the ability of these high-surface-area ZnO/ZnCo2O4 heterostructured rods to enable improved electrolyte permeability and Li ion transfer, thereby enhancing their Li storage capability (similar to 900 mA center dot h center dot g(-1) at a rate of 45 mA center dot h center dot g(-1)) for Li ion battery electrodes.
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