期刊
NANO LETTERS
卷 14, 期 2, 页码 1085-1092出版社
AMER CHEMICAL SOC
DOI: 10.1021/nl404784d
关键词
Carbon nanotube; current collector; iodine; aqueous cathode; redox batteries
类别
资金
- RIKEN
- short-term program of RIKEN International Program Associate (IPA)
- Cockrell School of Engineering at the University of Texas at Austin
- National Research Foundation of Korea [2010-00285]
- Ministry of Science, ICT & Future Planning, Republic of Korea [IBS-R014-D1-2014-A00] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2013K1A3A1A32035430] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A lithium-iodine (Li-I-2) cell using the triiodide/iodide (I-3(-)/I-) rcdox couple in an aqueous cathode has superior gravimetric and volumetric energy densities (similar to 330 W h kg(-1) and similar to 650 W h L-1, respectively, from saturated I-2 in an aqueous cathode) to the reported aqueous Li-ion batteries and aqueous cathode-type batteries, which provides an opportunity to construct cost-effective and high-performance energy storage. To apply this I-3(-)/I- aqueous cathode for a portable and compact 3.5 V battery, unlike for grid-scale storage as general target of redox flow batteries, we use a three-dimensional and millimeter thick carbon nanotube current collector for the I-3(-)/I- redox reaction, which can shorten the diffusion length of the redox couple and provide rapid electron transport. These endeavors allow the Li-I-2 battery to enlarge its specific capacity, cycling retention, and maintain a stable potential, thereby demonstrating a promising candidate for an environmentally benign and reusable portable battery.
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