期刊
NANO LETTERS
卷 12, 期 1, 页码 310-314出版社
AMER CHEMICAL SOC
DOI: 10.1021/nl203599y
关键词
Polymer electrolyte membrane; lithium ion battery; holographic polymerization; ion conductivity
类别
资金
- NSF [CMMI-0900162, DMR-0804838, DGE-0654313]
- Directorate For Engineering [0900162] Funding Source: National Science Foundation
Polymer electrolyte membranes (PEMs) with high and controlled ionic conductivity are important for energy-related applications, such as solid-state batteries and fuel cells. Herein we disclose a new strategy to fabricate long-range ordered PEMs with tunable ion conducting pathways using a holographic polymerization (HP) method. By incorporating polymer electrolyte into the carefully selected HP system, electrolyte layers/channels with length scales of a few tens of nanometers to micrometers can be formed with controlled orientation and anisotropy; ionic conductivity anisotropy as high as 37 has been achieved.
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