期刊
NANO LETTERS
卷 10, 期 2, 页码 603-609出版社
AMER CHEMICAL SOC
DOI: 10.1021/nl903636r
关键词
Nanoparticle; polymer; Janus; wetting; plasmon
类别
资金
- National Science Foundation (NSF) [DMR-0548070]
- NSF/MRSEC [DMR05-20020]
- NSF/Polymer Program [DMR-0549307]
- NSF/NSEC [DMR04-25780]
- Aston Fellowship (UPenn)
- Pennsylvania Muscle Institute (UPenn)
Multiregion and patchy optically active Janus particles were synthesized via a hierarchical self-assembly process. Gold nanoparticles were assembled on the top surfaces of nano- and submicrometer silica particles, which were selectively protected on their bottom surfaces by covalent attachment to a copolymer film. The morphologies of the gold particle layer, and the resulting optical properties of the Janus particles, were tuned by changing the surface energy between the silica and gold particles, followed by annealing.
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