期刊
NANO LETTERS
卷 10, 期 1, 页码 255-262出版社
AMER CHEMICAL SOC
DOI: 10.1021/nl9034187
关键词
Nanobelts; nanogrooves; stacking faults; nanoindentation; elastic modulus
类别
资金
- National Science Foundation [CMMI-0653651, CMMI-0824728, EPS-0296165]
- Army Research Office [W911NF-080299]
- ACS Petroleum Research Fund [ACS PRF 40450AC10]
- University of South Carolina NanoCenter
Single crystalline Ca2B2O5 center dot H2O (CBOH) nanobelts were synthesized for the first time Using a facile catalyst-free hydrothermal method at low temperature. After being annealed at 400 degrees C for 10 h, the CBOH nanobelts transformed into curve-shaped Ca2B2O5(CBO) nanogrooves with ordered stacking fault arrays along the [(1) over bar 10] direction. The single crystalline CBOH nanobelts and the stacking faulted CBO nanogrooves provided a unique platform for investigating the effects of hydrated H2O and stacking faults on the mechanical properties of nanomaterials. Nanoindentation tests were performed directly on individual CBOH nanobelts and CBO nanogrooves to probe their mechanical properties. It was found that the CBOH nanobelts, with the presence of hydrated H2O, achieved 28.7% increase in elastic modulus, whereas the stacking Faulted CBO nanogrooves, with the absence of hydrated H2O, exhibited 99% loss in elastic modulus, compared to bulk CBO.
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