期刊
MRS BULLETIN
卷 35, 期 11, 页码 868-876出版社
CAMBRIDGE UNIV PRESS
DOI: 10.1557/mrs2010.713
关键词
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资金
- U S Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001089]
- Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U S Department of Energy [DE-FG02-07ER15880]
Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies Departures from established structural trends for actinyl ions are provided by cation-cation interactions in which an O atom of one actinyl ion is an equatorial ligand of a bipyramid of another actinyl ion The solid-state structural complexity of actinide materials has been further demonstrated by open framework materials with interesting properties The U(VI) tetraoxide core has been added to this cation's repertoire of coordination possibilities The emergence of pentavalent uranium solid-state and coordination chemistry has resulted from the prudent selection of ligands Finally, analogues of the uranyl ion have challenged our understanding of this normally unreactive functional group
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