Infrared spectroscopy and integrated molar absorptivity of C60 and C70 fullerenes at extreme temperatures

The detection of C-60 and C-70 fullerenes in young planetary nebulae and in reflection nebulae suggests that these molecules are more common in certain astrophysical environments than previously thought. The dependence on temperature of the positions and widths of the infrared bands of the C-60 and C-70 fullerenes is needed for a firm qualitative detection of these molecules in space. Furthermore, the integrated molar absorptivity Psi (in km mol-1) of each infrared absorption band is required for a quantitative determination of the abundance of C-60 and C-70 in space. In this paper, we report on the temperature dependence of the wavelength shift and integrated molar absorptivity of the infrared bands of the C-60 and C-70 fullerenes. The measurements have been made in a KBr matrix in the temperature range between -180 degrees C and +250 degrees C. The experimental data have been extrapolated to derive both the infrared band shift and the integrated molar absorptivity of the C-60 and C-70 fullerenes at absolute zero temperature.