期刊
MOLECULES
卷 23, 期 10, 页码 -出版社
MDPI
DOI: 10.3390/molecules23102481
关键词
self-assembly; POSS; copolymer; amphiphile
资金
- Natural Science Foundation of China [51702178, 21606138]
- Taishan Scholar Program of Shandong [0308150303]
- Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province
Understanding the mechanism of molecular self-assembly to form well-organized nanostructures is essential in the field of supramolecular chemistry. Particularly, amphiphilic copolymers incorporated with polyhedral oligomeric silsesquioxanes (POSSs) have been one of the most promising materials in material science, engineering, and biomedical fields. In this review, new ideas and research works which have been carried out over the last several years in this relatively new area with a main focus on their mechanism in self-assembly and applications are discussed. In addition, insights into the unique role of POSSs in synthesis, microphase separation, and confined size were encompassed. Finally, perspectives and challenges related to the further advancement of POSS-based amphiphilics are discussed, followed by the proposed design considerations to address the challenges that we may face in the future.
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