期刊
MOLECULES
卷 23, 期 8, 页码 -出版社
MDPI
DOI: 10.3390/molecules23081935
关键词
silica aerogel; corrosion; silylation agent; ambient pressure drying
资金
- National Key Research and Development Program of China [2017YFB0603601-03]
- National Natural Science Foundation of China [21171014]
- State Key Laboratory of Solid Waste Reuse for Building Materials [SWR-2014-010]
The silica aerogels were prepared via a sol-gel technique and ambient pressure drying by using industrial solid wastes, dislodged sludges, as raw materials. A strategy was put forward to reduce the corrosion of equipment during the drying procedure. The pore structure, hydrophobicity, and thermal insulation property of the obtained samples were investigated in detail. The results show that the corrosion can be effectively avoided by using an equimolar mixture of trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDS) as silylation agents. At a Si:TMCS:HMDS molar ratio of 1:0.375:0.375, the silica aerogels possess a desirable pore structure with a pore volume of 3.3 +/- 0.1 cm(3)/g and a most probable pore size of 18.5 nm, a high hydrophobicity with a water contact angle of 144.2 +/- 1.1 degrees, and a low thermal conductivity of 0.031 +/- 0.001 W/(m.K).
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