期刊
MOLECULES
卷 16, 期 6, 页码 5020-5034出版社
MDPI AG
DOI: 10.3390/molecules16065020
关键词
asymmetric catalyst; bidentate phosphoramidite ligand; ruthenium catalyzed arylation
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [B01]
- Grants-in-Aid for Scientific Research [22550092] Funding Source: KAKEN
A ruthenium-catalyzed asymmetric arylation of aliphatic aldehydes and alpha-ketoesters with arylboronic acids has been developed, giving chiral alkyl(aryl)methanols and alpha-hydroxy esters in good yields. The use of a chiral bidentate phosphoramidite ligand (Me-BIPAM) achieved excellent enantioselectivities.
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