期刊
MOLECULES
卷 15, 期 5, 页码 3441-3461出版社
MOLECULAR DIVERSITY PRESERVATION INTERNATIONAL-MDPI
DOI: 10.3390/molecules15053441
关键词
palladium; nanoparticles; ionic liquids; cross-coupling; Heck; Suzuki; Stille; Sonogashira; Ullmann
资金
- Alexander-von-Humboldt Foundation
- CNPq
A brief summary of selected pioneering and mechanistic contributions in the field of carbon-carbon cross-coupling reactions with palladium nanoparticles (Pd-NPs) in ionic liquids (ILs) is presented. Five exemplary model systems using the Pd-NPs/ILs approach are presented: Heck, Suzuki, Stille, Sonogashira and Ullmann reactions which all have in common the use of ionic liquids as reaction media and the use of palladium nanoparticles as reservoir for the catalytically active palladium species.
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