期刊
MOLECULES
卷 15, 期 7, 页码 4908-4923出版社
MDPI
DOI: 10.3390/molecules15074908
关键词
solar energy conversion and storage; hydrogen energy; photocatalysis; platinum(II) catalysts; ruthenium complexes; molecular devices
资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [17205008, 18002016, 21350036]
- Grants-in-Aid for Scientific Research [21350036] Funding Source: KAKEN
With the aim of developing new molecular devices having higher photohydrogen-evolving activity, Pt(ppy)ClX units (ppy = 2-phenylpyridinate, X = Cl- or DMSO; DMSO = dimethylsulfoxide) have been employed as an H-2-evolving site, as the catalytic activity of [Pt(ppy)Cl-2](-) was confirmed to be higher than those of other mononuclear platinum(II) complexes. In the present study, two new heterodinuclear Ru(II)Pt(II) complexes, produced by condensation of [Ru(bpy)(2)(5-amino-phen)](2+) (bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline) with [Pt(cppy)Cl-2](-) and Pt(cppy)(DMSO) Cl (cppy = 9-carboxy-phenylpyridinate), respectively, have been prepared and their photo-hydrogen-evolving activities have been evaluated in detail. The ineffectiveness of these systems as photo-hydrogen-evolving molecular devices are interpreted in terms of their negative driving forces for the photoinduced electron transfer from the triplet MLCT excited state of the Ru chromophore to the pi*(ppy) orbital of the catalyst moiety.
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