期刊
MOLECULES
卷 15, 期 10, 页码 7235-7265出版社
MDPI AG
DOI: 10.3390/molecules15107235
关键词
protecting group; stereoselectivity; glycosylation; carbohydrate
资金
- National Natural Science Foundation of China [20732001]
- Ministry of Science and Technology of China [2009ZX09501-011]
Saccharides are polyhydroxy compounds, and their synthesis requires complex protecting group manipulations. Protecting groups are usually used to temporarily mask a functional group which may interfere with a certain reaction, but protecting groups in carbohydrate chemistry do more than protecting groups usually do. Particularly, protecting groups can participate in reactions directly or indirectly, thus affecting the stereochemical outcomes, which is important for synthesis of oligosaccharides. Herein we present an overview of recent advances in protecting groups influencing stereoselectivity in glycosylation reactions, including participating protecting groups, and conformation-constraining protecting groups in general.
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