期刊
MOLECULES
卷 15, 期 8, 页码 5782-5796出版社
MDPI
DOI: 10.3390/molecules15085782
关键词
alpha-aminophosphonate derivatives; aldimines; cinnamaldehyde; chiral organocatalyst; asymmetric addition
资金
- National Key Project for Basic Research [2010CB126105]
- National Natural Science Foundation of China [20872002]
Asymmetric addition under mild conditions of dialkyl phosphites on aldimines derived from cinnamaldehyde catalyzed by the inexpensive chiral organocatalyst (R)-3,3'-[4-fluorophenyl](2)-1,1'-binaphthol phosphate has been found effective to give new alpha-amino-phosphonates 9 in moderate yields (30-65%) and enantiomeric excess (8.4%-61.9%).
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