期刊
MOLECULES
卷 15, 期 11, 页码 8327-8348出版社
MDPI AG
DOI: 10.3390/molecules15118327
关键词
multifunctional catalyst; thiourea; Ru-catalyzed Huisgen cycloaddition; asymmetric induction; hydrogen bonding
资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- Takeda Science Foundation
The synthesis and properties of multifunctional thioureas bearing a variety of functional groups at a position remote from the thiourea moiety are described. A 1,5-disubstituted triazole tether connected with a thiourea and another functional group was synthesized via ruthenium catalyzed Huisgen cycloaddition. We demonstrate the utility of the synthetic thioureas as asymmetric catalysts and probes for the mechanistic elucidation of the course of the Michael reaction of an alpha,beta-unsaturated imide.
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